On the free radical redox chemistry of 5,6-dihydroxyindole

نویسندگان

چکیده

The poly-indolequinone polymers such as poly-dopamine and melanin are significant materials for advanced soft in coatings devices. In order to make progress towards a holistic thermodynamic model, one can consider the thermodynamics of redox chemistry key monomer building block: 5,6-dihydroxyindole. work presented here indicates new observation, that quinone methide tautomer plays role semiquinone free radical production. modelling includes set pH dependent, reduction potential equations account tautomerisation. Furthermore, estimations various variables. 1 electron is between 0.14 0.17 V (NHE); Semiquinone ?0.10 ?0.068 Tautomarisation constant estimated be 0.99 3.9; Comproportionation formation 3.8 × 103 50 103. may form basis understanding charge transport properties poly-indolequinones.

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ژورنال

عنوان ژورنال: Chemical Physics

سال: 2021

ISSN: ['0301-0104', '1873-4421']

DOI: https://doi.org/10.1016/j.chemphys.2021.111158